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How, using simple manual tests, can I identify an unknown plastic material?

TWI Frequently asked questions

Here are five simple tests which should help you identify the main industrially used thermoplastics. Please take appropriate precautions when doing burn tests and using sharp tools.

Use the tests in conjunction with the table of observations below.



Test no.Action
1.Look at the sample. Is it transparent, translucent or opaque?
2.Feel the sample. Does it bend? Can it be scratched? What does the surface feel like?
3.Cut the sample with a sharp knife. Does it cut easily? Are the edges smooth or jagged? Does it crumble or flake?
4.Subject the sample to a float test. Does it float or sink? (Note: not applicable to expanded foam materials. Water should be around room temperature).
5.Try to burn a small piece of the sample. What is the size and colour of the flame? Do molten drips fall from the sample and continue to burn? Does the sample self-extinguish? Is there any odour when the flame hasbeen extinguished?


MaterialTest no.Observation
Low density
polyethylene
(LDPE)
1Transparent only as thin film, translucent in thicker sections
2Fairly flexible; soft, 'waxy' feel, easily scratched
3Easily and smoothly cut
4Floats
5Not self-extinguishing; molten droplets which usually go out on reaching bench or floor; blue flame with yellow tip and little smoke, smell of burning candle/paraffin when flame is extinguished
High density
polyethylene
(HDPE)
1Transparent only as thin film, translucent in thicker sections
2Fairly stiff and hard, can be scratched by fingernail
3Easily cut with smooth edges
4Floats
5Not self-extinguishing; molten droplets which usually go out on reaching bench or floor; blue flame with yellow tip and little smoke, smell of burning candle/paraffin when the flame is extinguished
Polypropylene
(PP)
1Transparent only as thin film, translucent in thicker sections
2Stiff; hard, can be scratched by fingernail
3Easily cut, fairly smooth edges, when cut with chisel leaves white mark
4Floats
5Not self-extinguishing; molten droplets which usually go out on reaching bench or floor; flame mainly yellow with a trace of clear blue at the bottom; smell of burning candle/diesel when flame is extinguished.
Polyvinyl Chloride, Unplasticised
(uPVC)
1Transparent (unless fillers or pigments have been added)
2Stiff; hard
3Fairly easy to cut, smooth edges
4Sinks
5Burns with difficulty, self-extinguishing; yellow flame, blue-green at bottom edges; unpleasant, acrid odour of hydrochloric acid.